Hi Shaun,
My mistake that was a file I had previously uploaded into SmartVault through Method, not the other way around. So no you cannot upload a document into SV and have it show up in Method, it would have to be uploaded to SmartVault through Method CRM. Additionally, if you are using QuickBooks Online, you won't be able to see those documents in QuickBooks since SmartVault hasn't released their QBO integration yet. For now you would need to upload into Method for those documents to appear in QBO.
You cannot link more than one Method user per SmartVault account, and if you could it would be kind of meaningless for the free member since you only get 25MB of storage on SV.
- Ashur